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Because chemical reactions are usually associated with the rearrangement of charged particles such as electrons and atomic nuclei, chemical and electrical phenomena are closely linked. Chemical transformation occurring owing to the external applied electrical current or leading to generation of electrical current is studied in electrochemistry.

Electrochemical water treatment is related to the physicalechemical water treatment methods. Electrochemical treatment is characterized by multistage and relative complexity of physical and chemical phenomena occurring in electrochemical reactors (electrolyzers). The mechanism and rate of occurrence of the individual reaction steps are dependent on many factors, which have to be identified to determine the optimal reactor design and conditions for its operation.